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Largest problem with manure, including human manure in this case, is the algal blooms that result from the phosphorous and nitrogen getting into water. That can cause eutrophication that can cause the collapse of entire ecosystems. But of course with proper sewage treatment this risk is minimized. You peeing in the lake while swimming is more akin to the bush by the lakeside dropping leaves. However when it's an entire town's untreated sewage then it's a whole other issue and the results can be catastrophic.
But yes 1 tonne of pure tensides is much worse than 1 ton of poop. However poop tends to come in humongous quantities which is where the real problem lies.